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Beilstein J. Org. Chem. 2022, 18, 1210–1216, doi:10.3762/bjoc.18.126
Beilstein J. Org. Chem. 2022, 18, 732–737, doi:10.3762/bjoc.18.73
Graphical Abstract
Scheme 1: Historic synthetic approaches.
Figure 1: Resonance forms of isocyanides.
Scheme 2: Comparison between the previous mechanochemical synthetic pathway [24] and the new adapted one in this ...
Scheme 3: The scope of our isocyanide synthesis using aliphatic and aromatic primary formamides. Reaction con...
Figure 2: The purification process of a brownish isocyanide on a short silica pad.
Scheme 4: Suggested proton transfer mechanism.